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Chao Shi, Huibin Sun, Xiao Tang, Wen Lv, Prof. Dr. Hong Yan, Qiang Zhao, Jingxia Wang and Wei Huang Variable Photophysical Properties of Phosphorescent Iridium(III) Complexes Triggered by closo- and nido-Carborane Substitution Angewandte Chemie International Edition 52

Version of Record online: 16 OCT 2013 | DOI: 10.1002/anie.201307333

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Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

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