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Dr. Xiu-Hua Xu, Misaki Taniguchi, Xin Wang, Etsuko Tokunaga, Prof. Dr. Tomohiro Ozawa, Prof. Dr. Hideki Masuda and Prof. Dr. Norio Shibata Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O[RIGHTWARDS ARROW]Cvinyl and N[RIGHTWARDS ARROW]Cvinyl Trifluoromethanesulfonyl Migration Reactions Angewandte Chemie International Edition 52

Version of Record online: 15 OCT 2013 | DOI: 10.1002/anie.201307535

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Six transformations, one pot: Various di- and trisubstituted vinyl triflones, as well as several heteroaryl triflones, were stereoselectively synthesized from easily accessible gem-dibromovinyl substrates (see scheme, Boc=tert-butoxycarbonyl). The highlights of this synthetic method lie in the remote O[RIGHTWARDS ARROW]Cvinyl or N[RIGHTWARDS ARROW]Cvinyl triflyl migrations and the one-pot, three-step protocol.

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