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Sarah Z. Tasker, Dr. Alicia C. Gutierrez and Prof. Timothy F. Jamison Nickel-Catalyzed Mizoroki–Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products Angewandte Chemie International Edition 53

Article first published online: 8 JAN 2014 | DOI: 10.1002/anie.201308391

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Branching out: A Ni-catalyzed Heck reaction for the preparation of 1,1-disubstituted alkenes is presented. High selectivity for the branched products is achieved with electronically unbiased aliphatic terminal olefins. Regioselectivities remain consistently high (≥19:1) throughout. TESOTf=triethylsilyl trifluoromethanesulfonate.

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