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Dr. Shubhankar Kumar Bose, Dr. Katharina Fucke, Prof. Dr. Lei Liu, Prof. Dr. Patrick G. Steel and Prof. Dr. Todd B. Marder Zinc-Catalyzed Borylation of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents at Room Temperature Angewandte Chemie International Edition 53

Version of Record online: 13 JAN 2014 | DOI: 10.1002/anie.201308855

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Coupling a la carte: A catalytic system based on a ZnII N-heterocyclic carbene precursor has been developed for the cross-coupling reaction of alkyl halides with diboron reagents (see scheme). This is a novel use of a Group 12 catalyst for C[BOND]X borylation. IMes=1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene.

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