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Dr. Florian Schlütter, Dr. Tomohiko Nishiuchi, Dr. Volker Enkelmann and Prof. Dr. Klaus Müllen Octafunctionalized Biphenylenes: Molecular Precursors for Isomeric Graphene Nanostructures Angewandte Chemie International Edition 53

Version of Record online: 13 JAN 2014 | DOI: 10.1002/anie.201309324

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Carbon allotropes: A straightforward method for the octafunctionalization of biphenylene based on the [2+2]-cycloaddition of an aryne intermediate has been developed. This enabled the synthesis of isomeric graphene nanoribbons, [n]phenylenes, and nanographenes with even-membered rings embedded in a hexagonal lattice.

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