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Prof. Angiolina Comotti, Dr. Silvia Bracco, Prof. Teng Ben, Prof. Shilun Qiu and Prof. Piero Sozzani Molecular Rotors in Porous Organic Frameworks Angewandte Chemie International Edition 53

Version of Record online: 8 JAN 2014 | DOI: 10.1002/anie.201309362

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Fast molecular dynamics and large sorption capacity were combined in porous organic frameworks. The low-density, yet robust covalent architectures sustain extremely rapid rotational motion of the phenylene rings up to high temperatures. Porosity enables modulation of rotor dynamics by chemical stimuli: linear alkanes and iodine vapors, pervading the material, regulate rotor speed at will.

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