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Rui Ma, Wenyue Hao, Xiaolei Ma, Ye Tian and Prof. Yongdan Li Catalytic Ethanolysis of Kraft Lignin into High-Value Small-Molecular Chemicals over a Nanostructured α-Molybdenum Carbide Catalyst Angewandte Chemie International Edition 53

Version of Record online: 2 JUN 2014 | DOI: 10.1002/anie.201402752

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Krafty upgrade of a waste product: Kraft lignin was fully depolymerized into C6–C10 liquid products (see scheme) over a nanostructured α-molybdenum carbide catalyst in supercritical ethanol. In this process, which can be regarded as a fundamental finding for the upgrade of Kraft lignin to bio-oils under mild conditions, lignin fragments are rapidly stabilized with ethanol on the surface of the catalyst.

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