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Akshai Kumar and Ashoka G. Samuelson Catalytic Reactions of Titanium Alkoxides with Grignard Reagents and Imines: A Mechanistic Study Chemistry – An Asian Journal 5

Version of Record online: 16 JUN 2010 | DOI: 10.1002/asia.200900711

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Common ground: Isotopically labeled substrates show that intermediates involved in catalytic and stoichiometric reactions of Ti(OiPr)4 with Grignard reagents differ, although under both conditions they can be trapped with imines to yield common products in different ratios (see scheme).

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