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Dr. Jian-Bo Xie, Prof. Jian-Hua Xie, Xiao-Yan Liu, Qian-Qian Zhang and Prof. Qi-Lin Zhou Chiral Iridium Spiro Aminophosphine Complexes: Asymmetric Hydrogenation of Simple Ketones, Structure, and Plausible Mechanism Chemistry – An Asian Journal 6

Article first published online: 15 DEC 2010 | DOI: 10.1002/asia.201000716

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The chiral iridium complexes of spiro aminophosphine ligands were demonstrated to be highly efficient catalysts for the hydrogenation of aromatic ketones, providing chiral alcohols in high enantioselectivities (up to 97 % ee) with high turnover number (TON up to 10 000) and turnover frequency (TOF up to 3.7×104 h−1).

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