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Fei Sun, Fang Hu, Dr. Guanxin Zhang and Prof. Dr. Deqing Zhang Metal-Ion-Promoted Electron Transfer between Tetrathiafulvalene and Quinone Units Within a Calix[4]arene Framework and Tuning through Coordination of the Neighboring Crown Ether with a Sodium Cation Chemistry – An Asian Journal 7

Version of Record online: 4 OCT 2011 | DOI: 10.1002/asia.201100560

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Turn on/switch off: The intramolecular electron transfer between tetrathiafulvalene (TTF) and quinone units within calix[4]arene 1 occurs efficiently in the presence of Zn2+/Sc3+/Pb2+, and moreover the electron transfer within 1 triggered by Zn2+ can be switched off upon addition of Na+ and further turned on by further addition of either Sc3+ or Pb2+ (see scheme).

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