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Dr. Guang Lu, Chenlong Cui, Weina Zhang, Yayuan Liu and Prof. Fengwei Huo Synthesis and Self-Assembly of Monodispersed Metal-Organic Framework Microcrystals Chemistry – An Asian Journal 8

Article first published online: 12 OCT 2012 | DOI: 10.1002/asia.201200754

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How to make super latt(ic)e: Monodispersed octahedral microcrystals of a zirconium-carboxylate metal-organic framework (MOF), UiO-66, were synthesized, under optimized experimental conditions, by using acetic acid as a modulator. Due to their uniform size and shape, the obtained MOF microcrystals can be assembled not only into large-area two-dimensional (2D) monolayers with oriented facets through a liquid-air interfacial assembly technique, but also into long-range three-dimensional (3D) superlattices by sedimentation.

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