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Yusuke Fukahori, Yohei Takayama, Takuya Imaoka, Dr. Osamu Iwamoto and Prof. Dr. Kazuo Nagasawa Intramolecular 1,3-Dipolar Cycloaddition-Mediated Stereoselective Synthesis of Disubstituted Cyclopentane: A Simple Model for the Cyclopentane Ring System of Polycyclic Oroidine Alkaloids Chemistry – An Asian Journal 8

Version of Record online: 18 OCT 2012 | DOI: 10.1002/asia.201200820

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The mask of Oro: The disubstituted cyclopentane ring framework which is found in oroidine alkaloids such as axinellamine A was synthesized. The contiguous stereogenic centers at C11 and C16 involving a nitrogen-containing quaternary carbon center were constructed by intramolecular 1,3-dipolar cycloaddition.

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