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Jian Wang, Prof. Dr. Sheng-Qing Xia and Prof. Dr. Xu-Tang Tao A10LaCdSb9 (A=Ca, Yb): A Highly Complex Zintl System and the Thermoelectric Properties Chemistry – An Asian Journal 8

Version of Record online: 19 OCT 2012 | DOI: 10.1002/asia.201200827

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New lanthanum-doped complex Zintl phases, Ca10LaCdSb9 and Yb10LaCdSb9, have been designed and synthesized by using Zintl concepts. Their polyanion structures can be viewed as a random mixture between the [ASb6] octahedra and the [Cd2Sb6] dimerized tetrahedra, which results in extremely low lattice thermal conductivity.

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