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Yoshiaki Ueda, Yusuke Tanigawa, Prof. Chitoshi Kitamura, Prof. Hiroshi Ikeda, Yuichi Yoshimoto, Mirai Tanaka, Prof. Kazuhiko Mizuno, Prof. Hiroyuki Kurata and Prof. Takeshi Kawase 3,14-Bis(p-nitrophenyl)-17,17-dipentyltetrabenzo[a,c,g,i]-fluorene: A New Fluorophore Displaying Both Remarkable Solvatochromism and Crystalline-Induced Emission Chemistry – An Asian Journal 8

Article first published online: 13 DEC 2012 | DOI: 10.1002/asia.201200976

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A fluorophore displaying both large solvatochromism and CIE: A series of 17,17-dialkyl-3,14-diaryltetrabenzofluorenes including the 3,14-bis(p-nitrophenyl) derivative were prepared by using Suzuki–Miyaura cross-coupling reactions. The fluorescence of the dinitro derivative in aqueous THF exhibits a considerably large solvent effect (Δλem>90 nm) and crystalline-induced emission (CIE).

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