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Xing Huo, Changgui Zhao, Gaoyuan Zhao, Shouchu Tang, Huilin Li, Dr. Xingang Xie and Prof. Dr. Xuegong She PtCl2-Catalyzed Tandem Enyne Cyclization/1,2 Ester Migration Reaction Controlled by Substituent Effects of All-Carbon 1,6-Enynyl Esters Chemistry – An Asian Journal 8

Version of Record online: 20 FEB 2013 | DOI: 10.1002/asia.201300018

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On the move: A novel PtCl2-catalyzed tandem 1,6-enyne cyclization/1,2-acyloxy migration reaction was developed, which was shown to be controlled by substitution effects. Using this method, a series of substituted enol esters containing the cyclopentenyl motif were prepared in moderate to high yields.

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