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Wei-Kun Wang, Yuan-Yuan Chen, Dr. Hui Wang, Prof. Dr. Dan-Wei Zhang, Prof. Dr. Yi Liu and Prof. Dr. Zhan-Ting Li Tetrathiafulvalene-Based Macrocycles Formed by Radical Cation Dimerization: The Role of Intramolecular Hydrogen Bonding and Solvent Chemistry – An Asian Journal 9

Article first published online: 19 FEB 2014 | DOI: 10.1002/asia.201301729

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A dime(rization) a dozen: Inherently weak dimerization of tetrathiafulvalene (TTF) radical cations can be strengthened remarkably if two TTF units are attached to a hydrogen-bonding-driven aromatic amide foldamer segment and oxidized to TTF⋅+. The dimerization can lead to the formation of a uni- or bimolecular noncovalent macrocycle, depending on the polarity of the solvent.

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