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Sibongile Mafu, Dr. Matthew L. Hillwig and Prof. Dr. Reuben J. Peters A Novel Labda-7,13E-dien-15-ol-Producing Bifunctional Diterpene Synthase from Selaginella moellendorffii ChemBioChem 12

Version of Record online: 12 JUL 2011 | DOI: 10.1002/cbic.201100336

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Two-in-one enzyme: A bifunctional diterpene synthase from the lycophyte Selaginella moellendorffii has been characterized. The structure of its product, labda-7,13E-dien-15-ol, demonstrates that this enzyme catalyzes a novel class II diterpene cyclization reaction, and clarifies the biosynthetic origins of the family of derived natural products.

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