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Daniela Boettger and Christian Hertweck Molecular Diversity Sculpted by Fungal PKS–NRPS Hybrids ChemBioChem 14

Version of Record online: 7 DEC 2012 | DOI: 10.1002/cbic.201200624

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It's all in the mix: The combination of polyketides and amino acids gives rise to a diverse group of secondary metabolites. In fungi, the underlying biosynthetic enzymes code for type I iterative PKS–NRPS hybrids. This review provides an overview of all characterized fungal PKS–NRPS hybrids and their biosynthetic machinery, and highlights molecular engineering approaches.

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