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Dr. Madina Mansurova, Julian Simon, Dr. Susanne Salzmann, Prof. Dr. Christel M. Marian and Prof. Dr. Wolfgang Gärtner Spectroscopic and Theoretical Study on Electronically Modified Chromophores in LOV Domains: 8-Bromo- and 8-Trifluoromethyl-Substituted Flavins ChemBioChem 14

Article first published online: 1 MAR 2013 | DOI: 10.1002/cbic.201200670

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Vision in blue: Flavin derivatives, substituted at position 8 (R=bromo-, trifluoromethyl-) were synthesized and incorporated as chromophores into the blue-light-sensing LOV domain of YtvA from Bacillus subtilis. The resultant strong change in electronegativity significantly modifies the electronic and functional properties of the reconstituted LOV domains.

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