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Fiora Rosati and Gerard Roelfes Artificial Metalloenzymes ChemCatChem 2

Article first published online: 8 APR 2010 | DOI: 10.1002/cctc.201000011

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The best of both worlds: Artificial metalloenzymes have emerged as a promising approach to merge the attractive properties of homogeneous and biocatalysis. In this Review, the design and optimization strategies and the catalytic scope of artificial metalloenzymes are discussed, with a particular focus on the role of the second coordination sphere.

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