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Dr. Wolfgang Müller, Dr. Anina Wöhl, Stephan Peitz, Dr. Normen Peulecke, Dr. Bhaskar R. Aluri, Dr. Bernd H. Müller, Dr. Detlef Heller, Prof. Dr. Uwe Rosenthal, Dr. Mohammed H. Al-Hazmi and Fuad M. Mosa A Kinetic Model for Selective Ethene Trimerization to 1-Hexene by a Novel Chromium Catalyst System ChemCatChem 2

Article first published online: 22 JUN 2010 | DOI: 10.1002/cctc.201000052

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Caught in the model: A numerical model has been developed for the kinetics of the selective trimerization of ethene to 1-hexene by a homogeneous catalyst system comprising [CrCl3(thf)3], a Ph2PN(iPr)P(Ph)N(iPr)H ligand, and triethylaluminum. The model calculations and experimental data are in excellent agreement. In conjunction with mechanistic investigations, the model helps to elucidate the complex reaction network.

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