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Inge Geukens, Dr. Jan Fransaer and Dr. Dirk E. De Vos Aromatic Amination of Aryl Chlorides Catalyzed by Ni Nanoparticles in Aliphatic Phosphonium-Based Ionic Liquids ChemCatChem 3

Version of Record online: 1 JUL 2011 | DOI: 10.1002/cctc.201100073

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It doesn′t cost a dime: A nickel-based system that catalyzes the aromatic amination of aryl chlorides is presented. Starting from a simple Ni(II) salt, aliphatic phosphonium-based ionic liquids (ILs) were found to stabilize the nickel nanoparticles formed in situ during the reaction. The IL also enables successful recycling of the system after the reaction.

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