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Dr. Saravanan Gowrisankar, Dr. Helfried Neumann and Prof. Dr. Matthias Beller Palladium-Catalyzed Synthesis of Arylpropargyl Ethers ChemCatChem 3

Version of Record online: 10 JUN 2011 | DOI: 10.1002/cctc.201100075

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Adamant about this: A variety of aryl and heteroaryl propargyl ethers are obtained in good to excellent yields from activated and non-activated aryl bromides and chlorides in the presence of a sterically hindered, air-stable ligand by using a general palladium-catalyzed synthesis. Our protocol complements the known syntheses for alkynyl aryl ethers and 2H-1-benzopyrans and should find further applications in organic synthesis.

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