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Dr. Holger Klein, Dr. Ralf Jackstell, Dr. Thomas Netscher, Dr. Werner Bonrath and Prof. Dr. Matthias Beller Rhodium-Catalyzed Cyclocarbonylation of Alkynes to Hydroquinones ChemCatChem 3

Version of Record online: 27 JUN 2011 | DOI: 10.1002/cctc.201100095

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Cycle surprise: Ethyne as well as phenylactylene react with synthesis gas to hydroquinones in the presence of a Rh-phosphine catalyst. Especially in case of phenylacetylene, the presence of ammonia is essential for the reaction.

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