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G. M. Arzac, Dr. T. C. Rojas and Dr. A. Fernández Boron Compounds as Stabilizers of a Complex Microstructure in a Co-B-based Catalyst for NaBH4 Hydrolysis ChemCatChem 3

Version of Record online: 14 JUN 2011 | DOI: 10.1002/cctc.201100101

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Co-ddling together: Boron and cobalt chemistry allow for stabilization of a complex architecture on the nanoscale for a widely used CoB catalyst. Through nanoscale-resolution microscopy and spectroscopy techniques, the amorphous B-based phases, which stabilize the unusually small 1–3 nm hcp Co0 nanoparticles, are identified. This microstructure explains the high catalytic activity for the generation of hydrogen from sodium borohydride.

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