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Prof. Feng-Shou Xiao, Dr. Bin Xie, Haiyan Zhang, Liang Wang, Dr. Xiangju Meng, Prof. Weiping Zhang, Prof. Xinhe Bao, Dr. Bilge Yilmaz, Dr. Ulrich Müller, Prof. Hermann Gies, Dr. Hiroyuki Imai, Prof. Takashi Tatsumi and Prof. Dirk De Vos Interlayer-Expanded Microporous Titanosilicate Catalysts with Functionalized Hydroxyl Groups ChemCatChem 3

Article first published online: 11 JUL 2011 | DOI: 10.1002/cctc.201100144

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Simple as that: A novel crystalline microporous titanosilicate (Ti-COE-4) with functionalized hydroxyl groups and medium micropore size (0.55 nm) is successfully synthesized through dimethylsilylation and calcination. The synergism of hydroxyl groups with active Ti sites in Ti-COE-4 significantly improves its catalytic activities in oxidation reactions.

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