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Dr. Ja Hun Kwak, Dr. Roger Rousseau, Dr. Donghai Mei, Dr. Charles H. F. Peden and Dr. János Szanyi The Origin of Regioselectivity in 2-Butanol Dehydration on Solid Acid Catalysts ChemCatChem 3

Version of Record online: 16 AUG 2011 | DOI: 10.1002/cctc.201100173

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It′s a suppressed reaction: Owing to the dispersive forces between the alkyl groups of adsorbed 2-butanol and the catalyst surface, the formation of trans-2-butene is suppressed in the dehydration of 2-butanol on γ-alumina.

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