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Dr. Mamoru Tobisu and Prof. Dr. Naoto Chatani Catalytic Hydrogenolysis of C[BOND]O Bonds in Aryl Ethers ChemCatChem 3

Version of Record online: 8 JUL 2011 | DOI: 10.1002/cctc.201100181

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The first cut is the deepest: Hydrogenolysis is now applicable to the inert C(aryl)[BOND]O bonds in aryl ethers by using a soluble nickel complex ligated by N-heterocyclic carbenes. The protocol is potentially useful in the depolymerization of aryl ether-based biopolymers, such as lignin and coal. COD: 1,5-cyclooctadiene.

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