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Dr. Ken Motokura, Kohei Nakayama, Dr. Akimitsu Miyaji and Prof. Toshihide Baba “Ligand-Consuming” Formation of Rhodium-Hydride Species from [Rh(OH)(cod)]2 Without any Additional Hydride Sources for Catalytic Olefin Isomerizations and Cyclobutene Synthesis ChemCatChem 3

Article first published online: 15 JUL 2011 | DOI: 10.1002/cctc.201100185

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Multiple talents: A coordinatively unsaturated rhodium-hydride (Rh[BOND]H) species is formed from [Rh(OH)(cod)]2 without any additional hydride sources. The formation of the Rh[BOND]H species is confirmed by using 1H NMR analysis and hydride transfer reactions using deuterated olefins. This Rh[BOND]H species displays excellent catalytic performances in the isomerization of olefins.

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