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Dr. Chen Zhao and Prof. Dr. Johannes A. Lercher Selective Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Cycloalkanes on Pd/C and HZSM-5 Catalysts ChemCatChem 4

Version of Record online: 14 NOV 2011 | DOI: 10.1002/cctc.201100273

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Suffocating phenols: A catalyst system consisting of Pd/C and HZSM-5 shows an extremely high selectivity in removing oxygen-containing groups (hydroxyl, methoxy, ketone, alkyl[BOND]O[BOND]aryl, and aryl[BOND]O[BOND]aryl) in lignin-derived substituted phenolic monomers and dimers through a metal-acid catalyzed cascade cleavage of C[BOND]O bonds in phenolic dimers and the integrated hydrogenation and dehydration reactions in water at 473 K.

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