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Dr. Christian Fischer, Dr. Stefan Schulz, Dr. Hans-Joachim Drexler, Carmen Selle, Dr. Matthias Lotz, Dr. Mathias Sawall, Prof. Dr. Klaus Neymeyr and Prof. Dr. Detlef Heller The Influence of Substituents in Diphosphine Ligands on the Hydrogenation Activity and Selectivity of the Corresponding Rhodium Complexes as Exemplified by ButiPhane ChemCatChem 4

Version of Record online: 17 NOV 2011 | DOI: 10.1002/cctc.201100277

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Buti in the eye of the beholder: The influence of substituents in ButiPhane ligands on the hydrogenation activity and selectivity of the corresponding rhodium complexes has been quantitatively assessed. In the hydrogenation of a series of prochiral olefins, improved selectivities were obtained by increasing the steric bulk of the substituents on the phospholane ring of the chiral ligand.

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