E-mail

E-mail a Wiley Online Library Link

Dr. Rajeev S. Assary and Dr. Larry A. Curtiss Thermochemistry and Reaction Barriers for the Formation of Levoglucosenone from Cellobiose ChemCatChem 4

Article first published online: 19 OCT 2011 | DOI: 10.1002/cctc.201100280

Thumbnail image of graphical abstract

Cellobiose jumps the barrier: High-level quantum mechanical studies show that the ether bond cleavage in cellobiose occurs through internal hydrogen transfer in the gas phase and that the activation energy required is similar to that required for activating cellulose. The reaction barriers are computed for various pathways for the formation of levoglucosenone from levoglucosan, and the most likely pathway requires a relatively low activation barrier compared to that for the activation of cellobiose.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

Choose captcha format: Image or Audio. Click here if you need help.

SEARCH