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Dr. Moumita Koley, Navid Dastbaravardeh, Dr. Michael Schnürch and Prof. Dr. Marko D. Mihovilovic Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp2 C[BOND]H Bonds of N-Aryl-2-amino Pyridine Derivatives ChemCatChem 4

Version of Record online: 13 JUN 2012 | DOI: 10.1002/cctc.201200155

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Anilinate, anilinate! A method for arylation of anilines directed by an N-2-pyridyl group is developed. The reaction is tolerant towards a large number of substituents on both the aniline and the boronic acid, which is used as aryl donor. Although often considered a permanent directing group, the pyridine group is removed efficiently to give ortho-arylated aniline derivatives.

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