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Haitao Tian, Shilei Mu, Prof. Hexing Li, Prof. Xiaqin Wu and Dr. Zhongqing Lu Electrode-driven Regioselective Oxidation of Cinnamyl Alcohol by use of Thin Biologically Active Chloroperoxidase Composite Films ChemCatChem 4

Version of Record online: 7 AUG 2012 | DOI: 10.1002/cctc.201200172

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A film worth watching: A composite film modified glassy carbon electrode comprising chitosan, chloroperoxidase, didodecyldimethylammonium bromide, and Nafion is used with in situ-generated H2O2 as a bio-electrocatalytic system for the oxidation of cinnamyl alcohol. A total cinnamyl alcohol yield of 51.8 % (cf. 7.6 % with the conventional biological system with equivalent enzyme consumption) and a total turnover number of 80 500 are achieved.

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