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Dongsheng Bai, Shuhui Duan, Long Hai and Prof. Dr. Huanwang Jing Carbon Dioxide Fixation by Cycloaddition with Epoxides, Catalyzed by Biomimetic Metalloporphyrins ChemCatChem 4

Version of Record online: 13 AUG 2012 | DOI: 10.1002/cctc.201200204

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A healthy fixation: Several main group metalloporphyrin complexes are prepared and used in CO2 fixation in a “green” synthesis of cyclic carbonates from epoxides and CO2. The catalytic activity order of biomimetic metalloporphyrinoids was AlIII>MgII>SnIV>SnII, which is attributable to the Lewis acidity of the metal center.

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