Thorsten vom Stein, Tobias Weigand, Carina Merkens, Prof. Jürgen Klankermayer and Prof. Walter Leitner Trimethylenemethane-Ruthenium(II)-Triphos Complexes as Highly Active Catalysts for Catalytic CO Bond Cleavage Reactions of Lignin Model Compounds ChemCatChem 5
R u ready for it yet? The reaction of [Ru(cod)(methallyl)2] with tripodal phosphine ligands of the TRIPHOS-type results in the formation of Ru-trimethylenemethane complexes. Evaluation of their catalytic properties revealed a high activity for hydrogen transfer and CO cleavage reactions including the hydrogen-free reductive cleavage of 2-aryloxy-1-arylethanols as model compounds for lignin linkages.
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