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Dr. Zili Wu, Dr. Meijun Li and Dr. Steven H. Overbury A Raman Spectroscopic Study of the Speciation of Vanadia Supported on Ceria Nanocrystals with Defined Surface Planes ChemCatChem 4

Article first published online: 2 AUG 2012 | DOI: 10.1002/cctc.201200243

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Shape matters: Nanoshaped ceria with defined surface planes offers a fairly homogeneous platform for anchoring vanadia species. The surface oxygen vacancy formation energy and amount of defect sites in these nanoshapes, determined by the surface plane of ceria, are found to control the reaction between ceria and vanadia to form CeVO4.

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