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Jianglin Hu, Qi Zhang, Zhenhong Guan, Prof. Dr. Yanlong Gu, Dr. Wanling Mo, Prof. Dr. Tao Li and Prof. Guangxing Li Palladium-Catalyzed Carbonylation of Chloroacetates to Afford Malonates: Controlling the Selectivity of the Product in a Buffer ChemCatChem 4

Version of Record online: 12 JUL 2012 | DOI: 10.1002/cctc.201200245

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A select few: Malonates were obtained in excellent yields and selectivities from the palladium-catalyzed carbonylation of chloroacetates in a weakly alkaline buffer solution without the formation of Pd black.

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