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Dr. Sungsik Lee, Dr. Marcel Di Vece, Dr. Byeongdu Lee, Dr. Sönke Seifert, Dr. Randall E. Winans and Dr. Stefan Vajda Support-dependent Performance of Size-selected Subnanometer Cobalt Cluster-based Catalysts in the Dehydrogenation of Cyclohexene ChemCatChem 4

Version of Record online: 27 AUG 2012 | DOI: 10.1002/cctc.201200294

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Assemble together, catalyze together: The catalytic activity and selectivity of subnanometer 27±4 atom cobalt clusters in the dehydrogenation of cyclohexene shows strong support dependency. The support-cluster interactions reflect in the evolution of the oxidation state of the clusters during the course of the reaction, as well as in the formation of a dynamically evolving nanoassembly on the MgO support.

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