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Guillermo Lázaro, Dr. Manuel Iglesias, Dr. Francisco J. Fernández-Alvarez, Dr. Pablo J. Sanz Miguel, Prof. Jesús J. Pérez-Torrente and Prof. Luis A. Oro Synthesis of Poly(silyl ether)s by Rhodium(I)–NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis ChemCatChem 5

Version of Record online: 11 SEP 2012 | DOI: 10.1002/cctc.201200309

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Getting stuck to rhodium: A new family of rhodium N-heterocyclic carbene (NHC) species is described. The chlorido derivative was immobilized on the inorganic support MCM-41. Both the homo- and heterogeneous catalysts are effective for the copolymerization of terephthalaldehyde and 1,1,3,3,5,5-hexamethyltrisiloxane, which affords the corresponding poly(silyl ether).

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