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Roberto Wojcieszak, Prof.  Eric M. Gaigneaux and Patricio Ruiz Direct Methyl Formate Formation from Methanol over Supported Palladium Nanoparticles at Low Temperature ChemCatChem 5

Article first published online: 19 NOV 2012 | DOI: 10.1002/cctc.201200325

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A real challenge: Very active supported palladium nanoparticles have been used as selective catalysts in the oxidation of methanol to methyl formate in the presence of oxygen, but only at low temperature. At higher temperature, methyl formate is not formed at all and the formation of CO2 is promoted.

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