E-mail a Wiley Online Library Link

Dr. Luca Rocchigiani, Dr. Gianluca Ciancaleoni, Dr. Cristiano Zuccaccia and Prof. Dr. Alceo Macchioni An Integrated NMR and DFT Study on the Single Insertion of α-Olefins into the M[BOND]C Bond of Group 4 Metallaaziridinium Ion Pairs ChemCatChem 5

Version of Record online: 23 SEP 2012 | DOI: 10.1002/cctc.201200341

Thumbnail image of graphical abstract

A pair of Group 4s: Group 4 metallaaziridinium ion pairs stoichiometrically react with α-olefins, such as 1-hexene and 2-methyl-1-heptene, to form stable five-membered heterocycles. An integrated NMR and DFT study indicates that the diastereoisomeric ratios of the products are dictated by thermodynamics and depend strongly on the olefin, but only marginally on the metal.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field