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Dr. Joseph A. Wright and Prof. Christopher J. Pickett Towards a Functional Model of the [FeFe]-Hydrogenase: Dihydrogen Oxidation ChemCatChem 4

Version of Record online: 7 AUG 2012 | DOI: 10.1002/cctc.201200348

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Hydrogen oxidation—irons do it, slowly: Camara and Rauchfuss have shown that dihydrogen can be oxidised by combining a {2Fe–2S} core, a basic amine group and an electron sink in the same molecule. This biomimetic approach turns over and may open the way for more active catalysts.

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