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Dr. Lapo Luconi, Dr. Andrea Rossin, Dr. Giulia Tuci, Stéphane Germain, Dr. Emmanuelle Schulz, Dr. Jérôme Hannedouche and Dr. Giuliano Giambastiani Intramolecular Hydroamination Reactions Catalyzed by Neutral and Cationic Group IV Pyridylamido Complexes ChemCatChem 5

Article first published online: 28 SEP 2012 | DOI: 10.1002/cctc.201200389

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Back to the future! State-of-the-art group IV metal polymerization catalysts are applied to intramolecular C[BOND]N bond-forming reactions. Cationic species show remarkable catalytic activities for the production of N-containing heterocycles from secondary amino alkenes. Additional studies on the amido precursors highlight the role of metal coordination environment on the final catalytic performance.

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