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Altug S. Poyraz, Sourav Biswas, Homer C. Genuino, Saminda Dharmarathna, Chung-Hao Kuo and Prof. Steven L. Suib Bimodification of Mesoporous Silicon Oxide by Coupled “In Situ Oxidation at the Interface and Ion Exchange” and its Catalytic Activity in the Gas-Phase Toluene Oxidation ChemCatChem 5

Article first published online: 30 OCT 2012 | DOI: 10.1002/cctc.201200429

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Modifying inner surface of mesopores: Manganese is loaded into mesoporous silicon oxides by in situ oxidation at the interface, improving catalytic activity for toluene oxidation after the second modification by the promoter ions (Cs+ and K+) through an ion exchange mechanism between the cations and the cetyltrimethylammonium ion (CTA+). MPS=mesoporous silicon oxide.

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