E-mail a Wiley Online Library Link

Dr. Andrés F. Cardozo, Dr. Eric Manoury, Dr. Carine Julcour, Dr. Jean-François Blanco, Prof. Henri Delmas, Dr. Florence Gayet and Prof. Rinaldo Poli Preparation of Polymer Supported Phosphine Ligands by Metal Catalyzed Living Radical Copolymerization and Their Application to Hydroformylation Catalysis ChemCatChem 5

Version of Record online: 30 JAN 2013 | DOI: 10.1002/cctc.201200446

Thumbnail image of graphical abstract

Controlled length polystyrene-supported PPh3 ligands are made by atom transfer radical polymerization, involving direct copolymerization of styrene and 4-diphenylphosphinostyrene (SDPP). Controlled Mn and low dispersity are obtained with low SDPP content (≤25 %). The performance of these polymeric ligands in rhodium-catalyzed hydroformylation of 1-octene is evaluated as a function of polymer length, degree of P incorporation, and P/Rh ratio.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field