Dr. Krishnan Venkatasubbaiah, Dr. Yan Feng, Dr. Tina Arrowood, Dr. Peter Nickias and Prof. Christopher W. Jones Soluble and Supported Molecular CoIII Catalysts for the Regioselective Ring-Opening of 1,2-Epoxyhexane with Methanol ChemCatChem 5
Cooperative cobalt catalysts: The regioselective ring-opening of 1,2-epoxyhexane with methanol is studied by using different soluble molecular, soluble supported, and insoluble polymeric CoIII catalysts. Non-coordinating, non-nucleophilic counterions are most effective and a cooperativity effect is found in the supported catalysts. Polymeric insoluble catalysts are recyled with only minor deactivation.
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