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Dr. Krishnan Venkatasubbaiah, Dr. Yan Feng, Dr. Tina Arrowood, Dr. Peter Nickias and Prof. Christopher W. Jones Soluble and Supported Molecular CoIII Catalysts for the Regioselective Ring-Opening of 1,2-Epoxyhexane with Methanol ChemCatChem 5

Article first published online: 12 NOV 2012 | DOI: 10.1002/cctc.201200494

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Cooperative cobalt catalysts: The regioselective ring-opening of 1,2-epoxyhexane with methanol is studied by using different soluble molecular, soluble supported, and insoluble polymeric CoIII catalysts. Non-coordinating, non-nucleophilic counterions are most effective and a cooperativity effect is found in the supported catalysts. Polymeric insoluble catalysts are recyled with only minor deactivation.

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