E-mail a Wiley Online Library Link

Rafael E. Rodríguez-Lugo, Dr. Mónica Trincado and Prof. Dr. Hansjörg Grützmacher Direct Amidation of Aldehydes with Primary Amines under Mild Conditions Catalyzed by Diolefin-Amine–RhI Complexes ChemCatChem 5

Article first published online: 12 OCT 2012 | DOI: 10.1002/cctc.201200495

Thumbnail image of graphical abstract

Rhodium teaches toleration: The diolefin-amine–RhI complex [Rh(OTf)(trop2NH)(PPh3)] (see scheme) is an effective pre-catalyst for the amidation of a wide range of aldehydes with primary amines. The corresponding amides are obtained in good-to-excellent yields under very mild reactions conditions and a variety of functional groups are tolerated.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

Choose captcha format: Image or Audio. Click here if you need help.