Angelo Meduri, Dr. Tiziano Montini, Prof. Dr. Fabio Ragaini, Prof. Dr. Paolo Fornasiero, Prof. Ennio Zangrando and Dr. Barbara Milani Palladium-Catalyzed Ethylene/Methyl Acrylate Cooligomerization: Effect of a New Nonsymmetric α-Diimine ChemCatChem 5
Di(e)imine another day: Pd–dmso complexes with α-diimines are synthesized, characterized, and applied to ethylene/methyl acrylate cooligomerization. The complex with a new nonsymmetric α-diimine and dmso was found to be highly productive and showed a long catalyst lifetime. In the graphic, cat=[Pd(CH3)(L)(Ar-BIAN)][PF6].
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