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Angelo Meduri, Dr. Tiziano Montini, Prof. Dr. Fabio Ragaini, Prof. Dr. Paolo Fornasiero, Prof. Ennio Zangrando and Dr. Barbara Milani Palladium-Catalyzed Ethylene/Methyl Acrylate Cooligomerization: Effect of a New Nonsymmetric α-Diimine ChemCatChem 5

Article first published online: 5 NOV 2012 | DOI: 10.1002/cctc.201200520

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Di(e)imine another day: Pd–dmso complexes with α-diimines are synthesized, characterized, and applied to ethylene/methyl acrylate cooligomerization. The complex with a new nonsymmetric α-diimine and dmso was found to be highly productive and showed a long catalyst lifetime. In the graphic, cat=[Pd(CH3)(L)(Ar-BIAN)][PF6].

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